教授
电话:010-64428803
E-mail:zhangshu@mail.buct.edu.cn
办公室:无机楼421
研究领域
用于催化烯烃可控配位聚合的具有高催化活性和共聚性能的金属有机催化剂的设计合成研究,乙烯与其它烯烃单体的可控配位聚合反应研究,以及通过催化剂设计和聚合反应得到的高性能弹性体的结构与性能的研究。主要研究方向如下:
(1)金属有机催化剂的设计合成;
(2)烯烃可控配位聚合研究;
(3)高性能聚烯烃弹性体研究。
1999. 9~2003. 6 北京化工大学,应用化学,理学学士
2003.9~2008. 9 中国科学院化学研究所,高分子化学与物理,理学博士
2011.1至今,北京化工大学材料科学与工程学院,副教授,教授
2010.10~2010.12,首都大学东京(Tokyo Metropolitan University),助教
2010.04~2010.10,首都大学东京(Tokyo Metropolitan University),日本学术振兴会(JSPS) 外国人特别研究员
2008.10~2010.04,奈良先端科技大学院大学(Nara Institute of Science and Technology),日本学术振兴会(JSPS) 外国人特别研究员
科研成果:
主要从事烯烃配位聚合催化剂及烯烃可控配位聚合反应研究。作为项目负责人,近5年承担/完成国家自然科学基金项目2项,企事业单位委托项目3项。在国内外重要学术期刊发表论文50余篇(SCI收录40余篇)、申请专利近20余项(已授权6项)。
代表性学术论文 (10-15篇)
1. Shu Zhang, Na Wu, and Yi-Xian Wu*. Highly Cis-1,4 Selective Polymerization of Conjugated Dienes Catalyzed by N-heterocyclic Carbene-ligated Neodymium Complexes. Chinese J. Polym. Sci. 2020, 38, 1305-1312.
2. Xiaoxian Xue, Li Tian, Song Hong, Shu Zhang*, Yixian Wu*, Effects of Composition and Sequence of Ethylene-Vinyl Acetate Copolymers on Their Alcoholysis and Oxygen Barrier Property of Alcoholyzed Copolymers, Ind. Eng. Chem. Res., 2019, 58, 4125−4136.
3. Shu Zhang, Wen-Chao Zhang, Dan-Dan Shang, Yi-Xian Wu*. Synthesis of ultra-high molecular weight ethylene-propylene copolymer via quasi-living copolymerization with N-heterocyclic carbene ligated vanadium complexes. J. Polym. Sci. Part A: Polym. Chem., 2019, 57, 553-561.
4. 张树,张志乾,吴一弦*.先进催化剂及其用于乙烯/丙烯配位共聚的研究进展,科学通报,in press.
5. 张树,吴一弦*,烯烃可控聚合及其大分子工程,中国科学:化学,2018,48,590-600.
6. Zhi-Qian Zhang, Jun-Teng Qu, Shu Zhang*, Qiu-Ping Miao, Yi-Xian Wu*, Ethylene/propylene copolymerization catalyzed by half-titanocenes containing monodentate anionic nitrogen ligands: effect of ligands on catalytic behaviour and structure of copolymer, Polym. Chem., 2018,9,48-59.
7. Shu Zhang#, Wenjuan Zhang#, Kotohiro Nomura*, Synthesis and Reaction Chemistry of Alkylidene Complexes With Titanium, Zirconium, Vanadium, and Niobium: Effective Catalysts for Olefin Metathesis Polymerization and Other Organic Transformations. Adv. Organomet. Chem., 2017, 68, 93-136.
8. Shu Zhang,* Wenchao Zhang, Dandan Shang, Zhiqian Zhang and Yixian Wu*, Ethylene/propylene copolymerization catalyzed by vanadium complexes containing N-heterocyclic carbenes, Dalton Trans., 2015, 44, 15264-15270.
9. Shu Zhang, Matthias Tamm, Kotohiro Nomura*. 1,2-C-H Activation of Benzene Promoted by (Arylimido)-vanadium(V)-Alkylidene Complexes: Isolation of the Alkylidene, Benzyne Complexes.Organometallics, 2011, 30, 2712-2720.
10. Kotohiro Nomura*, Shu Zhang. Design of new generation vanadium complex catalysts for precise olefin polymerization.Chem. Rev., 2011, 111, 2342-2362.
11. Shu Zhang, Kotohiro Nomura*. Highly efficient dimerization of ethylene by (imido)vanadium complexes containing ((2-anilidomethyl)pyridine ligands: notable ligand effect toward activity and selectivity. J. Am. Chem. Soc., 2010, 132, 4960-4965.
12. Shu Zhang, Wen-Hua Sun*, XiangHao, Tianpengfei Xiao. Ferrous and cobaltous chlorides bearing 2,8-bis(imino)quinolines: highly active catalysts for ethylene polymerization at high temperature. Organometallics, 2010, 29,1168-1173.
授权国家发明专利
1. 吴一弦,张志乾,张树,何兰霞,张腾,王云杰. 一种用于烯烃聚合的钒基催化体系,专利号:ZL201610030967.3。
2. 吴一弦,张志乾,张树,妙秋平. 含有茂金属化合物的催化剂体系及其催化烯烃聚合的方法,专利号:ZL201611231866.9。
3. 吴一弦,张树,曲俊腾,张志乾. 一种茂金属催化剂体系及其催化烯烃聚合的方法,专利号:ZL201611231860.1。