郭隆海 副教授

郭隆海

副教授/硕导
办公电话:010-64419631
E-mail:guolh@mail.buct.edu.cn

研究领域;
1.可控自由基聚合
2. 功能高分子涂层材料的合成与应用
3. 聚合反应的在线光谱分析和在线检测方法研究

2001.9-2005.7:北京化工大学 获学士学位
2005.9-2008.7:北京化工大学 获硕士学位
2008.10-20011.9:关西学院大学(日本) 获博士学位

2012.3-2014.6:北京化工大学 博士后
2014.6 - 至今:北京化工大学 副教授


科研情况概述:

采用可控自由基聚合方法,制备具有链段结构可控的两亲性多嵌段共聚物,通过在线光谱分析技术原位研究聚合诱导自组装机理和形貌演化动力学,并拓展在自修复材料、智能水凝胶材料、药物缓释材料等功能材料领域的应用研究。

 

代表论文:

1. Zhujun Huang, TengQiu, Huangbing Xu, Haotian Shi, JianlingRui,Xiaoyu Li and Longhai Guo*,Surfactant-Free Visible-Light-Controlled Emulsion Polymerization toward ABA-Type Amphiphilic Triblock Copolymers, Macromolecules,2018, 51, 7329−7337.

2. Liangdong Zhang, TengQiu, Zhiqiang Zhu, Longhai Guo* and Xiaoyu Li,Self-Healing Polycaprolactone Networks through Thermo-Induced Reversible Disulfide Bond Formation, Macromol. Rapid Commun.2018, 1800121.

3. Minhua Yi, TengQiu, Masayoshi Okubo,Xiaoyu Li and Longhai Guo*,Innovative on-line near-infrared (NIR) spectroscopy to estimate content of each phase in composite polymer particles prepared by seeded emulsion polymerization, Vibrational Spectroscopy,2018, 95, 23–31.

4. Qi Li, Longhai Guo, TengQiu, Jun Ye, Lifan He, Xiaoyu Li, XinlinTuo, Polyurethane/polyphenylsilsequiloxane nanocomposite: From waterborne dispersions to coating films, Progress in Organic Coating, 2018, 122, 19-29.

5. YanlingJia, TengQiu, Longhai Guo, Jun Ye, Lifan He,Xiaoyu Li, Reduction−Coagulation Preparation of Hybrid Nanoparticles of Graphene and Halloysite Nanotubes for Use in Anticorrosive Waterborne Polymer Coatings, ACS Appl. Nano Mater.,2018, 1, 1541−1550.

6. ZhiQiao,TengQiu,Weiwei Liu, Liangdong Zhang, JinqiangTu, Longhai Guo* andXiaoyu Li, A “green” method for preparing ABCBA penta- block elastomers by using RAFT emulsion polymerization, Polym. Chem., 2017, 8, 3013.

7. ZhiQiao, TengQiu,Weiwei Liu, Longhai Guo* and Xiaoyu Li, Novel tri-block copolymers of poly(acrylic acid)- b-poly(2,2,3,3,4,4,4-hexafluorobutyl acrylate)- b-poly(acrylic acid) prepared via two-step RAFT emulsion polymerization, Polym. Chem., 2016, 7, 3993.

8. TengQiu, Xiaojing Wang,XiangyunLin, Zhiqiang Zhu, Xiaoyu Li andLonghai Guo*, Emulsion Polymerization to Synthesize Self-Healing Films Toward Healing on Fractures: A Feasible Strategy, Journal of Polymer Science, Part A: Polymer Chemistry,2016, 54, 3071–307.

9. Longhai Guo, Shanshan Ren, TengQiu, Leilei Wang, Jiangru Zhang, Lifan He,Xiaoyu Li, Synthesis of polystyrene@(silver–polypyrrole) core/shell nanocomposite microspheres and study on their antibacterial activities, J Nanopart Res,2015, 17, 47.

10. Longhai Guo, Yongjing Jiang, Siyu Chen, TengQiu,Xiaoyu Li, Self-Assembly of Poly(methacrylic acid)‐b‐poly(butyl acrylate) Amphiphilic Block Copolymers in Methanol via RAFT Polymerization and during Film Formation for Wrinkly Surface Pattern, Macromolecules,2014, 47, 165−174.

11. Longhai Guo, Yongjing Jiang, TengQiu, Yan Meng, Xiaoyu Li, One-pot synthesis of poly(methacrylic acid)-b-poly(2,2,2- trifluoroethyl methacrylate) diblock copolymers via RAFT polymerization,Polymer,2014, 55, 4601-4610.

12. Longhai Guo, Sijiu Jiang, TengQiu, Shengwen Zhang, Lifan He, Jie Tan, Xiaoyu Li, Miniemulsion Polymerization of Fluorinated Siloxane-Acrylate Latex and the Application as Waterborne Textile Finishing Agent, J. Appl. Polym. Sci.,2014, 40162.

 

专利:

1. 一种高环氧含量水性环氧/丙烯酸复合乳液的制备,CN201810510900.9

2. 一种固体酸催化合成非离子型乳化剂的方法及其应用,CN201810411618.5

3. 一种水性环氧/聚丙烯酸复合乳液及其制备方法,CN201610323877.3

4. 一种ABA型及ABCBA型嵌段共聚物及制备和应用,CN201610262599.5

5. 一种微球级交联聚合物空心微球及其制备方法,CN201510250999.X

 

科研项目:

1. 近红外光谱法研究核壳结构乳胶粒子的过渡相结构演化和合成可控化,国家自然科学基金青年基金项目

2. 轨道车辆用水性环氧防腐底漆规模化制备与应用,国家重点研发计划

 

学术**:

1. 中国近红外光谱学会,常务理事